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\u4e2d\u56fd\u662f\u5168\u7403\u6700\u5927\u7684\u7532\u9187\u751f\u4ea7\u56fd\u548c\u9700\u6c42\u56fd\uff0c\u968f\u7740\u4e8c\u6c27\u5316\u78b3\u52a0\u6c22\u5236\u7532\u9187\u6280\u672f\u7684\u52a0\u901f\u53d1\u5c55\uff0c\u65b0\u578b\u9ad8\u6548\u50ac\u5316\u5242\u5c42\u51fa\u4e0d\u7a77\uff0c\u50ac\u5316\u5242\u8868\u5f81\u548c\u8bc4\u4ef7\u5de5\u827a\u6301\u7eed\u4f18\u5316\u3002<\/p>\n\n\n\n

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CO2<\/sub>+3H2<\/sub>=CH3<\/sub>OH+H2<\/sub>O\u00a0\u00a0\u00a0\u00a0 \u00a0(1)<\/p>\n\n\n\n

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CO2<\/sub>+H2<\/sub>=CO+H2<\/sub>O               (2)<\/p>\n\n\n\n

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\u6c27\u5316\u94df\u662f\u4e00\u79cd\u7a81\u7834\u6027\u7684\u4e8c\u6c27\u5316\u78b3\u52a0\u6c22\u5236\u7532\u9187\u50ac\u5316\u5242\uff0cJavier P\u00e9rez-Ram\u00edrez\u8bfe\u9898\u7ec4\u91c7\u7528\u5bf9\u6bd4\u5171\u6c89\u6dc0\u6cd5\u548c\u6d78\u6e0d\u6cd5\u5236\u5907\u4e86\u954d-\u6c27\u5316\u94df\u50ac\u5316\u5242\uff0c\u901a\u8fc7Micromeritics AutoChem HP II <\/strong>\u4e0a\u5b8c\u6210\u7684H2<\/sub>-TPR @ 5Mpa pressure (\u4e0b\u56fe\u4e0a) <\/strong>\u7814\u7a76\u4e86\u954d\u7684\u5f62\u6001\uff0c\u5728\u7ea6340 K\u65f6\u53d1\u751f\u6c27\u5316\u954d\u5411\u91d1\u5c5e\u954d\u7684\u8f6c\u5316\uff0c\u5728370 K\u65f6\u53d1\u751f\u8868\u9762\u6c27\u5316\u94df\u7684\u8fd8\u539f\u3002Micromeritics AutoChem II 2920 <\/strong>\u4e0a\u5b8c\u6210\u7684CO-TPD(\u4e0b\u56fe\u4e0b)<\/strong>\u8bc1\u5b9e\uff0c\u5f53\u91d1\u5c5e\u4e0e\u6c27\u5316\u94df\u63a5\u89e6\u65f6\uff0c\u954d\u5bf9\u4e00\u6c27\u5316\u78b3\u5206\u5b50\u5438\u9644\u7684\u8d21\u732e\u660e\u663e\u8f83\u4f4e\u3002\u8fd9\u4e9b\u53d1\u73b0\u8868\u660e\u4e86\u663e\u8457\u7684\u7535\u5b50\u6548\u5e94\uff0c\u5373\u91d1\u5c5e-\u8f7d\u4f53\u76f8\u4e92\u4f5c\u7528\u548c\/\u6216\u954d\u548c\u94df\u7684\u5408\u91d1\u5316[3]\u3002Javier P\u00e9rez-Ram\u00edrez\u8bfe\u9898\u7ec4\u5206\u522b\u5728Tristar II\u548c<\/strong> ASAP 2020<\/strong>\u4e0a\u6d4b\u8bd5N2<\/sub>\u5438\u9644\u7b49\u6e29\u7ebf<\/strong>\u533a\u5206\u4e0d\u540c\u65b9\u6cd5\u751f\u6210\u7684\u954d-\u6c27\u5316\u94df\u50ac\u5316\u5242BET\u6bd4\u8868\u9762\u79ef\u5dee\u5f02\u4ee5\u53ca\u6c27\u5316\u94df\u5728\u50ac\u5316\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u7684BET\u6bd4\u8868\u9762\u79ef\u53d8\u5316\u3002Micromeritics AutoChem II 2920 <\/strong>\u4e0a\u5b8c\u6210\u7684H2<\/sub>-TPR<\/strong>\u3001CO2<\/sub>-TPD \u548cCO-TPR<\/strong>\u7b49\u8868\u5f81\u65b9\u6cd5\u7528\u4e8e\u9a8c\u8bc1\u6c27\u5316\u94df\u7684\u53ef\u8fd8\u539f\u6027\u548c\u6c27\u7a7a\u4f4d\uff08Ov<\/sub>\uff09\u3002Javier P\u00e9rez-Ram\u00edrez\u8bfe\u9898\u7ec4\u5c06\u6c27\u5316\u94df\u50ac\u5316\u5242\u88c5\u8f7d\u5728Micromeritics customized fixed-bed reactors<\/strong>\u8fdb\u884c\u50ac\u5316\u5242\u8bc4\u4ef7\uff0c\u8054\u7528\u5728\u7ebf\u6c14\u76f8\u8272\u8c31\u5206\u6790\u53cd\u5e94\u4ea7\u7269\u3002\u603b\u4f53\u800c\u8a00\uff0cJavier P\u00e9rez-Ram\u00edrez\u8bfe\u9898\u7ec4\u786e\u5b9a\u4e86\u63a7\u5236\u7ecf\u5178\u91d1\u5c5e\u954d\u4e0e\u6c27\u5316\u94df\u63a5\u89e6\u6027\u80fd\u7684\u5173\u952e\u7ed3\u6784\u548c\u7535\u5b50\u7279\u6027\uff0c\u4ece\u800c\u83b7\u5f97\u7a33\u5b9a\u7684\u53ef\u6301\u7eed\u6027\u5e94\u7528\u3002<\/p>\n\n\n

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\"\"<\/figure>\n<\/div>\n\n\n

\u4e0a\u9762\u7684\u51e0\u4e2a\u6848\u4f8b\u5145\u5206\u5c55\u793a\u4e86Micromeritics<\/strong>\u7684\u7269\u7406\u5438\u9644\u4eea\uff0c\u5316\u5b66\u5438\u9644\u4eea\u4ee5\u53ca\u50ac\u5316\u53cd\u5e94\u5668\u5728\u4e8c\u6c27\u5316\u78b3\u52a0\u6c22\u5236\u7532\u9187\u6280\u672f\u4e2d\u7684\u5e94\u7528\uff0c\u5e2e\u52a9\u79d1\u5b66\u5bb6\u6df1\u5165\u7406\u89e3\u50ac\u5316\u53cd\u5e94\u673a\u7406\uff0c\u5bf9\u4e8e\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u5177\u6709\u91cd\u8981\u7684\u610f\u4e49\u3002\u2002Micromeritics <\/strong>\u662f\u9897\u7c92\u3001\u7c89\u4f53\u548c\u591a\u5b54\u6750\u6599\u7684\u8868\u5f81\u9886\u57df\u7684\u5168\u7403\u9886\u5bfc\u8005\uff0c\u63d0\u4f9b\u6c14\u4f53\u5438\u9644\u3001\u5bc6\u5ea6\u3001\u7c89\u4f53\u6d41\u52a8\u3001\u50ac\u5316\u6d3b\u6027\u7b49\u591a\u79cd\u6280\u672f\uff0c\u81f4\u529b\u4e8e\u670d\u52a1\u4e8c\u6c27\u5316\u78b3\u52a0\u6c22\u5236\u7532\u9187\u7684\u50ac\u5316\u5242\u8868\u5f81\u548c\u8bc4\u4ef7\uff0c\u63a8\u52a8\u80fd\u6e90\u8f6c\u578b\u3001\u5b9e\u73b0\u78b3\u4e2d\u548c\u76ee\u6807\u3001\u4fc3\u8fdb\u73af\u4fdd\u548c\u7ecf\u6d4e\u53d1\u5c55\u3002<\/p>\n\n\n\n

<\/p>\n\n\n\n

\u53c2\u8003\u6587\u732e<\/h2>\n\n\n\n

[1] Journal of Fuel Chemistry and Technology<\/em>, 2024<\/strong>, 52, 12.<\/p>\n\n\n\n

[2] ACS Catalysis,<\/em> 2024<\/strong>, 14, 12610.<\/p>\n\n\n\n

[3] Nature Communication<\/em>, 2021, 12<\/strong>, 1960.<\/p>\n\n\n\n

[4] Angew Chemie International Edtion,<\/em> 2016<\/strong>, 55, 6261.<\/p>\n","protected":false},"excerpt":{"rendered":"

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